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Full Description
The demand for organosilicon elastomers used in the production of thermally resistant rubbers and organosilicon polymers for making non-metal composite materials is increasing from year to year.This monograph presents a discussion on the methods used for synthesizing and studying properties of newly designed organosilicon polymers, namely organosiloxane copolymers with cyclolinear structure of macromolecules.This book presents an overview of data on methods of synthesizing primary linear and cyclic organosiloxanes of various structures.This book will be of value and interest to researchers working in the field of chemistry of organosilicons.
Contents
PrefaceIntroductionChapter 1. Linear and cyclic organosiloxanesLinear and cyclic organosiloxanes with assigned disposition of functional groups at silicon atomsChapter 2. Organosilicon oligomers and copolymers of bead-shaped structureBead-shaped organosiloxane oligomers and copolymers with organocyclotetra(penta,hexa)siloxane fragments in the backboneBead-shaped methylphenylsiloxane copolymers with ethylene bridges between cyclesBead-shaped methylphenylsiloxane polymers with ethylene bridges between ringsOligomers and copolymers with organocyclocarbosiloxane fragments in the chainSilarylene cyclosiloxane and silarylene carborganocyclosiloxane oligomers and copolymersChapter 3. Copolymers with cyclic fragments in dimethylsiloxane backboneSiloxane cyclolinear copolymers with organocyclotetra(penta, hexa)siloxane fragments in dimethylsiloxane backboneCyclolinear copolymers with cyclic carbosiloxane fragments in dimethylsiloxane backboneOrganosiloxane copolymers with heterocyclic fragments in the dimethylsiloxane backbonePoly(organocarbosiloxanes) with cyclic siloxane fragments in the backboneCyclolinear copolymers derived by polymerization of organobicyclo- and organotricyclosiloxanesChapter 4. Organosilixane copolymers with cyclic fragments in the side chainSynthesis of monomeric difunctional organocyclosiloxanesSynthesis of organosiloxane copolymers with monocyclic (cyclotri-, cyclotetra-, cyclopentasiloxane) fragments in the side chainSynthesis of organosiloxane oligomers with cyclic fragments in the side chain by catalytic dehydrocondensationSynthesis of cyclolinear organosiloxane copolymers by hydrosilylationChapter 5. Organosilicon copolymers with carbocyclosiloxane fragments in dimethylsiloxane backboneSynthesis of organospirobicyclosiloxanes and organosprirobicyclosilazasiloxanesSynthesis of difunctional heterocyclic compoundsSynthesis and study of properties with organosilicon copolymers with cardocyclosiloxane fragmentsOrganosilicon copolymers with card-type heterocyclic fragments in the linear chainSynthesis and studies of properties of card-type organosilicon oligomers with silaoxadihydrophenentrene fragments in the chainChapter 6. Organosilicon copyolymers with bi-, tri- and tetracyclic structures in dimethylsiloxane backboneSynthesis of organobi-, organotri- and organotetracyclosiloxanes and bicyclocarbosiloxanes with functional groupsSynthesis of difunctional bicyclocarbosiloxanesSynthesis of organosilicon copolymers with organobi-, organotri- and organotetracyclosiloxane fragments in dimethylsiloxane backboneOrganosilicon copolymers with bicyclocarbosiloxane fragments in the backboneCarbosiloxane copolymers with tricyclic fragtments in the backboneChapter 7. Synthesis of organosilicon cyclolinear block-copolymersBlock-copolymers with poly(phenylsilsesquioxane) fragments in the dimethylsiloxane backboneReferences
