Organometallic Conjugation : Structures, Reactions and Functions (Springer Series in Chemical Physics Vol.73) （2003. XVI, 351 p. w. 285 figs. and 36 schemes.）

Organometallic Conjugation : Structures, Reactions and Functions (Springer Series in Chemical Physics Vol.73) （2003. XVI, 351 p. w. 285 figs. and 36 schemes.）

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  • 製本 Hardcover:ハードカバー版／ページ数 351 p., 285 figs.
  • 商品コード 9783540000884

Full Description

This volume presents a detailed account of the rapidly developing area known as "organometallic conjugation," encompassing organometallic chemistry and other important fields of chemistry, such as theoretical and computational chemistry, preparative and physical chemistry and bio-inorganic chemistry. The major feature of the concept centers on the novel orbital interactions between metal and carbon or similar elements, such as N, O, and S. After an introductory chapter on the history of this new field, recent theoretical and computational aspects are described. Further chapters address, among other things, application to suprazeolite microporous materials, organometallic catalysis in polymerization, orbital conjugation in metalloproteins, the role of hydrogen bonding in biochemical reactions and, finally, potential applications in the fields of soft molecular materials and molecular devices.

Contents

Organometallic Conjugation: Conceptual Advance and Research Prospects.- Theoretical Studies.- Mechanism of Nonlinear Optical Phenomena.- Structure and Dynamics of Manganese Oxide Clusters and Related Systems.- Extended Conjugation in Organometallic Complexes.- Suprazeolite Microporous Materials of Metal Carboxylates.- Dynamic, Electronic and Magnetic Properties of Metal-Ligand and Metal-Metal Interaction Systems.- Interaction between Transition Metals and Ancillary Ligands in Polymerization Catalysis.- Molecular Switching.- Metal-Hydrogen Bond Conjugated Systems.