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Full Description
Synthesis is one of the major endeavours of the organic chemist, and the design of a successful synthesis requires a sound knowledge of functional group chemistry, stereochemistry and organic reaction mechanisms. Organic Synthetic Methods introduces the major methods of creating carbon-carbon and carbon-nitrogen bonds, along with functional group interconversions (oxidation, reduction, halogenation). The use of protecting groups and solid-phase methods are also discussed. The analysis of the structure of a target molecule, in terms of the structural consequences of synthetic reactions, is introduced to enable the student to identify key dissections and building blocks and hence develop a suitable synthetic method. Examples of the synthesis of labelled compounds are also provided. Ideal for the needs of undergraduate chemistry students, Tutorial Chemistry Texts is a major new series consisting of short, single topic or modular texts concentrating on the fundamental areas of chemistry taught in undergraduate science courses. Each book provides a concise account of the basic principles underlying a given subject, embodying an independent-learning philosophy and including worked examples.
Contents
Introduction; Organometallic and ylide methods of carbon-carbon bond formation; Carbonyl activation and enolate chemistry in carbon-carbon bond formation; Carbocations in synthesis; Free radical and pericyclic reactions in the formation of carbon-carbon bonds; Methods of making carbon-nitrogen bonds; Functional group transformations; Protecting groups; Some examples of total syntheses; Further reading; Answers to problems; Subject index.