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Full Description
This work introduces an approach to the chemical structures of grain boundaries. It presents readers with practical, experimental techniques and includes information on advances in the field. A "grain" is a portion of a material which has all of its atoms in alignment, forming a crystal structure. The boundary or interface between two grains is the grain boundary. Grain boundaries are becoming increasingly important in the development of new materials, enabling the characterization of physical and mechanical properties of materials.
Contents
Boundaries and interfaces in materials - introduction; principles governing grain shape and size; size and orientation of grains; energy polycrystalline materials; diffusion; structure of boundaries and interfaces; composition of boundaries and interfaces; electronic structure; strength of grain boundaries; grain boundary composition: equilibrium segregation; non-equilibrium segregation; interphase boundaries; composition changes in materials: introduction; role of crystallography on composition; relationship between different surfaces; interfaces and boundaries; iron alloys and steels; non-ferrous alloys; non-metal systems; measurement of composition - introduction; indirect methods; direct methods; electron energy loss spectrometry; contrast analysis; auger; X-ray photoelectron spectroscopy; secondary ion mass spectroscopy; field ion and atom probe microscopy; scanning probe microscopy and atom force microscopy; mechanical properties: engineering requirements; fracture in materials; intergranular fracture; strength of grain boundaries; temper embrittlement; higher temperature and liquation embrittlement of steels; creep and creep fatigue; stress relief and reheat cracking; environmentally assisted cracking; irradiation damage; others.