Electrochemical Activation of Catalysis : Promotion, Electrochemical Promotion, and Metal-Support Interactions

個数：

Electrochemical Activation of Catalysis : Promotion, Electrochemical Promotion, and Metal-Support Interactions

  • 提携先の海外書籍取次会社に在庫がございます。通常3週間で発送いたします。
    【重要ご説明事項】
    1. 納期遅延や、ご入手不能となる場合が若干ございます。
    2. 複数冊ご注文の場合、分割発送となる場合がございます。
    3. 美品のご指定は承りかねます。
  • 【入荷遅延について】
    世界情勢の影響により、海外からお取り寄せとなる洋書・洋古書の入荷が、表示している標準的な納期よりも遅延する場合がございます。
    おそれいりますが、あらかじめご了承くださいますようお願い申し上げます。
  • ◆画像の表紙や帯等は実物とは異なる場合があります。
  • ◆ウェブストアでの洋書販売価格は、弊社店舗等での販売価格とは異なります。
    また、洋書販売価格は、ご注文確定時点での日本円価格となります。
    ご注文確定後に、同じ洋書の販売価格が変動しても、それは反映されません。
  • 製本 Hardcover:ハードカバー版／ページ数 574 p.
  • 言語 ENG
  • 商品コード 9780306467196
  • DDC分類 541.395

基本説明

Describes the phenomenology, theory and potential applications of the phenomenon of electrochemical promotion, where electrochemically induced ion spillover activates and controls heterogeneous catalysis.

Full Description

I knew nothing of the work of C. G. Vayenas on NEMCA until the early nineties. Then I learned from a paper of his idea (gas interface reactions could be catalyzed electrochemically), which seemed quite marvelous; but I did not understand how it worked. Consequently, I decided to correspond with Professor Vayenas in Patras, Greece, to reach a better understanding of this concept. I think that my early papers (1946, 1947, and 1957), on the relationship between the work function of metal surfaces and electron transfer reactions thereat to particles in solution, held me in good stead to be receptive to what Vayenas told me. As the electrode potential changes, so of course, does the work function at the interface, and gas metal reactions there involve adsorbed particles which have bonding to the surface. Whether electron transfer is complete in such a case, or whether the effect is on the desorption of radicals, the work function determines the strength of their bonding, and if one varies the work function by varying the electrode potential, one can vary the reaction rate at the interface. I got the idea. After that, it has been smooth sailing. Dr. Vayenas wrote a seminal article in Modern Aspects of Electrochemistry, Number 29, and brought the field into the public eye. It has since grown and its usefulness in chemical catalytic reactions has been demonstrated and verified worldwide.

Contents

Introduction, Brief History and Basic Concepts.- Promotion in Heterogeneous Catalysis.- Solid Electrolytes, Catalysis and Spillover.- Electrochemical Promotion of Catalytic Reactions.- Origin of NEMCA.- Rules and Modeling of Promotion.- The Absolute Potential.- Electrochemical Promotion with O2? Conductors.- Electrochemical Promotion with Cationic Conductors.- NEMCA with Aqueous Electrolytes and Inorganic Melts.- Electrochemical Promotion and Metal-support Interactions.- Practical Applications, Summary and Perspectives.