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基本説明
Topics covered include theory of bonding, structure and composition, catalytic properties, physical properties, new methods of preparation, spectroscopy and microscopy.
Full Description
This book arose from a symposium titled 'Transition Metal Carbides and Nitrides: Preparation, Properties, and Reactivity' organized by Jae Sung Lee, Masatoshi Nagai and myself. The symposium was part of the 1995 Congress of Pacific Rim Chemical Societies, held in Honolulu, Hawaii between December 17-22, 1995. The meeting was the first major conference to exclusively address the theme of metal carbides and nitrides, and brought together many of the major researchers in the field. Over 50 scientists and engineers reported their latest findings in five sessions of presentations and discussions. The book closely follows the topics covered in the conference: Theory of bonding Structure and composition Catalytic properties Physical properties New methods of preparation Spectroscopy and microscopy The book is unique in its coverage. It provides a general introduction to the properties and nature of the materials, but also covers their latest applications in a wide variety of fields. It should thus be of interest to both experts and nonexperts in the fields of material science, solid-state chemistry, physics, ceramics engineering, and catalysis. The first chapter gives an overview, and many of the chapters provide summaries of advanced topics. All contributions were peer-reviewed.
Contents
1 Introduction to the chemistry of transition metal carbides and nitrides.- Abstract.- 1.1 Introduction.- 1.2 Crystalline structure and composition.- 1.3 Bonding and electronic properties.- 1.4 Physical properties.- 1.5 Electric and magnetic properties.- 1.6 Preparation.- 1.7 Applications.- 1.8 Catalysis and surface studies.- References.- Physical Properties.- 2 Application of transition metal carbides and nitrides industrial tools.- 3 Review of diffusion and vaporization of Group 4 and 5 transition metal carbides.- 4 Chemical diffusion in transition metal-carbon and transition metal-nitrogen systems.- Theory.- 5 The origins of the similarities between late transition metals and early transition metal monocarbides.- 6 Fermi surface of hexagonal tungsten carbide.- 7 Orbital symmetry and superconductivity in carbides and borocarbides.- New Materials.- 8 Recent developments in ternary nitride chemistry.- 9 Transition metal-based double nitrides.- 10 Magnetic properties of rare earth-iron compounds containing carbon and/or nitrogen.- Synthesis.- 11 The synthesis of titanium nitride and titanium carbonitride by self-propagating combustion.- 12 Combustion synthesis of transition metal nitrides.- 13 New route to molybdenum nitrides and oxynitrides: preparation and characterization of new phases.- 14 Synthesis of thin films of Cr, Mo and W carbides and nitrides.- 15 Single-source precursors for the chemical vapor deposition of titanium and vanadium carbide and nitride.- Catalysis.- 16 Carbides of transition metals as catalysts for oxidation reactions.- 17 Surface molybdenum species and acid sites on nitrided moly bdena-alumina catalysts.- 18 Carbide-oxide interactions in bulk and supported tungsten carbide catalysts for alcohol synthesis.- 19 Fischer-Tropsch synthesis and XRD characterization of an iron carbide catalyst synthesized by laser pyrolysis.- 20 Study of the isomerization of C6 and C6+ alkanes over molybdenum oxycarbide catalysts.- 21 Characterization of oxygen-treated carbides of molybdenum and tungsten for n-hexane-dihydrogen reactions.- 22 Synthesis and catalytic properties of tungsten carbide for isomerization, reforming and hydrogenation.- Spectroscopy and Microscopy.- 23 Chemisorption of CO and NO molybdenum carbide foils.- 24 Characterization of the electronic and catalytic properties of vanadium carbide: a comparative study of VC/V(110) model surfaces and VC powder materials.- 25 Surface shifts in core level energies of transition metal carbides and nitrides.- 26 Study of the Auger metal peak of carbides and nitrides by factor analysis.- 27 Transition metal nitride and carbide nanoparticles.- 28 Carbide formation during activation of iron Fisher-Tropsch catalysts.- Indexes.
