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Full Description
Appropriate for advanced undergraduate and beginning graduate-level chemistry and chemical engineering courses in kinetics, chemical kinetics, and molecular interpretation. This best selling book offers a balanced presentation of the macroscopic view of empirical kinetics and the microscopic molecular viewpoint of chemical dynamics.* NEW - Revised to include the most up-to-date information throughout. * NEW - Discusses a range of new topics including heterogeneous reactions in atmospheric chemistry, reactant product imaging, and molecular dynamics of H + H2. * NEW - Discusses an experimental observation of the transition state ("Femtochemistry"). * NEW - Presents new treatment of stratospheric chemistry, including heterogeneous processes, balance among catalytic cycles, environmental consequences, and policy implications. * NEW - Presents current database information on NIST kinetics as well as JPL evaluations. * NEW - Separate combustion chapter. FEATURES * Stresses interconnections between phenomenological chemical kinetics and molecular reaction dynamics.* Discusses reactions in gas phase, liquids, and at surfaces; molecular potential surfaces; gas-gas and gas-surface theories applied to reactive collisions. * Features real-world problems and applications to atmospheric chemistry, combustion, and chemical lasers. * Presents multiple methods for solving kinetic equations. * Presents topics not addressed elsewhere. * Information theory. * Stochastic simulation. * Sensitivity analysis. * Includes over 150 figures, tables of Laplace Transforms, and over 125 problems and exercises. *Discusses a range of new topics including heterogeneous reactions in atmospheric chemistry, reactant product imaging, and molecular dynamics of H + H2.*Stresses interconnections between phenomenological chemical kinetics and molecular reaction dynamics.*Presents multiple methods for solving kinetic equations.*Presents topics not addressed elsewhere.*- Information theory; Stochastic simulation; Sensitivity analysis.
Contents
1. Basic Concepts of Kinetics. 2. Complex Reactions. 3. Kinetic Measurements. 4. Reactions in Solution. 5. Catalysis. 6. The Transition from the Macroscopic to the Microscopic Level. 7. Potential Energy Surfaces. 8. Dynamics of Biomolecular Collisions. 9. Experimental Chemical Dynamics. 10. Statistical Approach to Reaction Dynamics: Transition State Theory. 11. Unimolecular Reaction Dynamics. 12. Dynamics Beyond the Gas Phase. 13. Information-Theoretic Approach to State-to-State Dynamics. 14. Kinetics of Multicomponent Systems: Combustion Chemistry. 15. Kinetics of Multicomponent Systems: Atmospheric Kinetics. Appendix 1. Quantum Statistical Mechanics. Appendix 2. Classical Statistical Mechanics. Appendix 3. Databases in Chemical Kinetics.
